Okay, you've been posting good debut pics and consistently improving for a while now and I haven't bothered to say anything. Time to break that habit, I think.
Good pic. Those webs are very nicely done (and nice texture on the reds), though I'd personally have made them darker. They're so light right now that they make the spider logo pop out a bit more than it should, it looks kinda floaty.
And speaking of floaty: the eyes. They don't look like they're part of the mask, but more as though they're pasted on it, I think largely cause of the bevel effect.
On another note, the shape of the red part of his chest and the "belt" of his costume are assymettrical and look rather weird.
Very nice pic otherwise. The colours look be a bit oversaturated to my eye, but that's me. You continue to show improvement with each submission. Keep it up!